Measurements of water vapor total content in the solar spectrum of the atmosphere

  1. Zuev Institute of Atmospheric Optics SB RAS, Russia
  2. St.Petersburg University, Russia

   Registration of absorption spectra of solar radiation, passed through the
   the Earth's atmosphere, was carried out by the Fourier spectrometer
   IFS-125M. All spectra were recorded during the period of May 17-23, 2012.
   Conditions of spectrum registration: spectral range is 25,000 - 8000 cm-1
    (400 - 1250 nm); photodetector is silicon photodiode; the
   splitter is quartz; resolution is 0.05 cm-1; scanner speed is 20
   kHz; the diameter of the aperture is 0.6 mm; time of one measurement is 10
   minutes. The measurements were carried out with the diameter of the
   aperture of 0.85 mm (in this case, the signal to noise ratio (S/N) is
   increased by 2-3 times), however, spectrum distortion was observed in the
   high-frequency range of 400-500 nm. In the area of 18000 cm-1   S/N = 100.

  Spectrum registration during the mentioned period was carried
   out from 8-30 till 18-00. During the experiment, solar radiation was often
   covered by clouds. The results, obtained during the measurements, were
   processed by SFIT v3.92 program . In the result, the data on water vapor
   total content were obtained during the processing of experimental data in
   the range of 9900-10000 cm-1. Some intervals were selected:
   9979.4-9981.15 cm-1 and 9941-9958 cm-1 - in this case,
   the results of calculations of water vapor total content were the most
   stable.
  

   Н2О total content = 4.28х1022 mol/cm2
  

   Measurements of the Fourier-spectrometer were compared with the
   measurements of sun photometer. The difference with the first range
   (9979.4-9981.15 cm-1) was 1.2 percent.
   The work is partly supported by the Rusian Fund for Basic Research Grants,
   RAS Program 3.9.